Optical and electrochemical properties of tunable host-guest complexes linked to plasmonic interfaces
Résumé
This article describes the use of localized surface plasmon resonance (LSPR) interface to detect complexation/decomplexation steps of a controllable host–guest system at the solid–liquid interface. The LSPR interfaces consist of a sandwiched structure comprising a tin-doped indium oxide (ITO) substrate, gold nanostructures (Au NSs) and a thin ITO film overcoating. “Click” chemistry was used to covalently link an alkyne-functionalized π-electron deficient tetracationic cyclophane cyclobis(paraquat-p-phenylene) (CBPQT4+) unit to an azide-terminated LSPR interface. The modified interfaces were characterized using X-ray photoelectron spectroscopy (XPS), cyclic voltammetry and UV-vis transmission spectroscopy. Tetrathiafulvalene (TTF) was used as a model guest molecule to demonstrate the possibility to follow the complexation/decomplexation events by monitoring the change in the LSPR signal. The results demonstrate that redox controlled host–guest complexation at the surface can be monitored effectively using LSPR.
Domaines
MatériauxOrigine | Fichiers produits par l'(les) auteur(s) |
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