Sodium borohydride hydrolysis as hydrogen generator: issues, state of the art and applicability upstream from a fuel cell - Archive ouverte HAL
Article Dans Une Revue Fuel Cells Année : 2010

Sodium borohydride hydrolysis as hydrogen generator: issues, state of the art and applicability upstream from a fuel cell

Akdim Ouardia
  • Fonction : Auteur
Julien Hannauer
  • Fonction : Auteur
Rita Chamoun
  • Fonction : Auteur
Philippe Miele

Résumé

Today there is a consensus regarding the potential of NaBH4 as a good candidate for hydrogen storage and release via hydrolysis reaction, especially for mobile, portable and niche applications. However as gone through in the present paper two mains issues, which are the most investigated throughout the open literature, still avoid NaBH4 to be competitive. The first one is water handling. The second one is the catalytic material used to accelerate the hydrolysis reaction. Both issues are object of great attentions as that can be noticed throughout the open literature. This review presents and discusses the various strategies which were considered until now by many studies to manage water and to improve catalysts performances (reactivity and durability). Published studies show real improvements and much more efforts might lead to significant overhangs. Nevertheless the results show that we are still far from envisaging short-term commercialization.

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Chimie
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Dates et versions

hal-00552352 , version 1 (06-01-2011)

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Umit Bilge Demirci, Akdim Ouardia, Jérôme Andrieux, Julien Hannauer, Rita Chamoun, et al.. Sodium borohydride hydrolysis as hydrogen generator: issues, state of the art and applicability upstream from a fuel cell. Fuel Cells, 2010, 10 (3), pp.335. ⟨10.1002/fuce.200800171⟩. ⟨hal-00552352⟩
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