Breathing transitions in MIL-53(Al) metal-organic framework upon xenon adsorption.
Résumé
MOFs come alive: The combination of gas‐adsorption experiments at various temperatures with an osmotic thermodynamic model produced a generic temperature–loading phase diagram that displays unexpected re‐entrant behavior. The breathing effect in the metal–organic framework MIL‐53(Al) is predicted to be general and should be observed over a limited temperature range regardless of the guest adsorbate.
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