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Article Dans Une Revue International Journal of Quantum Chemistry Année : 2012

The Rayleigh-Schrödinger perturbation series of quasi-degenerate systems

Résumé

We present the first representation of the general term of the Rayleigh-Schrödinger series for quasidegenerate systems. Each term of the series is represented by a tree and there is a straightforward relation between the tree and the analytical expression of the corresponding term. The combinatorial and graphical techniques used in the proof of the series expansion allow us to derive various resummation formulas of the series. The relation with several combinatorial objects used for special cases (degenerate or non-degenerate systems) is established.
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Dates et versions

hal-00533128 , version 1 (05-11-2010)

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Christian Brouder, Gérard Duchamp, Frédéric Patras, Gabor Zsolt Toth. The Rayleigh-Schrödinger perturbation series of quasi-degenerate systems. International Journal of Quantum Chemistry, 2012, 112 (10), pp.2256-2266. ⟨10.1002/qua.23201⟩. ⟨hal-00533128⟩
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