Reflexion Mössbauer analysis of the in situ oxidation products hydroxycarbonate green rust
Résumé
The purpose of this study is to determine the nature of the oxidation products of FeII-III hydroxycarbonate FeII4FeIII2(OH)12CO3•3H2O (green rust GR(CO32-)) by using the miniaturised Mössbauer spectrometer MIMOS II. Two Mössbauer measurements methods are used: method (i) with green rust pastes coated with glycerol and spread into Plexiglas sample holders, and method (ii) with green rust pastes in the same sample holders but introduced into a gas-tight cell with a beryllium window under a continuous nitrogen flow. Method (ii) allows us to follow the continuous deprotonation of GR(CO32-) into the fully ferric deprotonated form FeIII6O4(OH)8CO3•3H2O by adding the correct amount of H2O2, without any further oxidation or degradation of the samples.
Domaines
Chimie-Physique [physics.chem-ph]Origine | Fichiers produits par l'(les) auteur(s) |
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