Sticking Properties of Water Clusters - Archive ouverte HAL
Article Dans Une Revue Physical Review Letters Année : 2010

Sticking Properties of Water Clusters

Sébastien Zamith
Pierre Labastie
  • Fonction : Auteur
  • PersonId : 917516
Jean-Marc L'Hermite

Résumé

Absolute attachment cross sections of single water molecules onto mass-selected protonated water clusters have been measured in the 30-200 size range and for collision energies down to ∼50 meV. The major surprise is that the attachment cross sections are always smaller or equal to the hard sphere cross section. The attractive interaction between water molecules and charged water nanodroplets does not enhance the sticking probability as expected. The attachment probability is reduced due to dynamical processes on a short time scale; that is, inelastic scattering occurs when the duration of the collision becomes smaller than the period of the O**O**O surface bending motion. A simple analytical expression is derived that gives the sticking probability of a water molecule onto a water nanodroplet in a vapor as a function of the vapor temperature and the size of the droplet.
Fichier principal
Vignette du fichier
h2Osigma_2nd_round.pdf (205.43 Ko) Télécharger le fichier
Origine Fichiers produits par l'(les) auteur(s)
Loading...

Dates et versions

hal-00506580 , version 1 (28-07-2010)

Identifiants

Citer

Sébastien Zamith, Pierre Feiden, Pierre Labastie, Jean-Marc L'Hermite. Sticking Properties of Water Clusters. Physical Review Letters, 2010, 104 (10), pp.103401. ⟨10.1103/PhysRevLett.104.103401⟩. ⟨hal-00506580⟩
143 Consultations
202 Téléchargements

Altmetric

Partager

More