An Undecanuclear FeIII Single-Molecule Magnet
Résumé
The undecanuclear complex in [FeIII 11(μ4-O)3(μ3-O)4(L)3(μ- O2CCMe3)12]Cl 3 5MeCN has been synthesized and characterized by single-crystal X-ray crystallography. M€ossbauer spectroscopy and bulk susceptibility studies reveal that the complex has an S = 13/2 spin ground state and exhibits single-molecule-magnet behavior.