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Article Dans Une Revue Carbohydrate Research Année : 2010

Solid-phase de novo synthesis of a (±)-2-deoxy-glycoside

Résumé

The solid-phase synthesis of methyl 2-deoxy-3-O-benzyl-d,l-arabino-hexopyranoside was achieved in a six-step sequence via a de novo strategy based on the hetero-Diels–Alder reaction of a vinyl ether supported on an azalactone-functionalized polystyrene resin, followed by the functional modification of the heteroadduct and the final release of the methyl glycoside by acidic solvolysis.

Dates et versions

hal-02355097 , version 1 (08-11-2019)

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Citer

Céline Lucchesi, Amélie Arboré, Sagrario Pascual, Laurent Fontaine, Christian Maignan, et al.. Solid-phase de novo synthesis of a (±)-2-deoxy-glycoside. Carbohydrate Research, 2010, 345 (6), pp.844-849. ⟨10.1016/j.carres.2010.01.017⟩. ⟨hal-02355097⟩
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