Order versus disorder in chiral tetrathiafulvalene-oxazoline radical-cation salts: structural and theoretical investigations and physical properties. - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemistry - A European Journal Année : 2010

Order versus disorder in chiral tetrathiafulvalene-oxazoline radical-cation salts: structural and theoretical investigations and physical properties.

Résumé

Electrocrystallization experiments with the chiral ethylenedithio-tetrathiafulvalene-methyl-oxazoline (EDT-TTF-OX) donors (R)-, (S)-, and (rac)-1 have provided two series of mixed-valence salts with the PF(6) (-) and [Au(CN)(2)](-) anions. Within each series the cell parameters are the same for the three R, S, and rac compounds, except for the space group, which is centrosymmetric triclinic P$\bar 1$ for the racemic forms and noncentrosymmetric P1 for the enantiopure salts. In the racemic salt [(rac)-1](2)PF(6) the two enantiomers crystallize disordered on the same crystallographic site with a site occupational factor of 0.6:0.4, whereas this type of disorder is not possible in the enantiopure salts. Both s-cis and s-trans conformations, when taking into account the mutual orientation of the TTF and oxazoline moieties, are present in this first series. In sharp contrast, in the series of salts [1](2)[Au(CN)(2)], only the s-trans conformation is observed with no structural disorder. Theoretical calculations at the DFT level of theory revealed a very small energy difference between the two stable planar s-cis and s-trans conformations, which are both energy minima in either neutral or oxidized states. Single-crystal conductivity measurements showed metallic-like behavior for all the salts down to 220-250 K with a smooth increase in resistivity at lower temperatures. The conductivity at room temperature is 5 S cm(-1) for [(rac)-1](2)PF(6), in which disorder was observed, whereas for [(R)-1](2)PF(6) and [(S)-1](2)PF(6) the average value is around 100 S cm(-1). In the second series of salts the conductivity at room temperature is 125-130 S cm(-1) for [(rac)-1](2)[Au(CN)(2)] and [(R)-1](2)[Au(CN)(2)]. Extended Hückel band structure calculations revealed identical features for the three salts of the [1](2)[Au(CN)(2)] series and are consistent with the electronic structures of quasi-one-dimensional conductors.

Dates et versions

hal-00468277 , version 1 (30-03-2010)

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Citer

Augustin M. Madalan, Céline Réthoré, Marc Fourmigué, Enric Canadell, Elsa B. Lopes, et al.. Order versus disorder in chiral tetrathiafulvalene-oxazoline radical-cation salts: structural and theoretical investigations and physical properties.. Chemistry - A European Journal, 2010, 16 (2), pp.528-37. ⟨10.1002/chem.200901980⟩. ⟨hal-00468277⟩
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