This paper describes a detailed performance evaluation of distributed Medium Access Control (MAC) protocols for Wireless Sensor Networks based on Impulse Radio Ultra Wideband (IR-UWB) Physical layer (PHY). Two main classes of Medium Access Control protocol have been considered: Slotted and UnSlotted with reliability. The reliability is based on Automatic Repeat ReQuest (ARQ). The performance evaluation is performed using a complete Wireless Sensor Networks (WSN) simulator built on the Global Mobile Information System Simulator (GloMoSim). The optimal operating parameters are first discussed for IR-UWB in terms of slot size, retransmission delay and the number of retransmission, then a comparison between IR-UWB and other transmission techniques in terms of reliability latency and power efficiency.