X-ray crystal structures of copper(II) and cobalt(II) complexes with Schiff base ligands. Reactivity towards dioxygen - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Dalton Transactions Année : 2003

X-ray crystal structures of copper(II) and cobalt(II) complexes with Schiff base ligands. Reactivity towards dioxygen

F. Carre
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Rjp Corriu
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E. Lancelle-Beltran
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A. Mehdi
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C. Reye
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R. Guilard
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J. Sykora
  • Fonction : Auteur
Arie van Der Lee

Résumé

Copper(II) and cobalt(II) Schiff base complexes with derivatives of the pentadentate ligand bis(salicylideneimino-3-propyl)amine [H(2)salDPT] have been prepared. The X-ray crystal structures of the copper(II) complexes Cu[salDPT] and Cu[sal(n-propyltrimethylsilyl)DPT] were determined and revealed five-coordination at the metal centre in both cases. The 1:1 dioxygen adduct of Co[sal(n-propyltrimethylsilyl)DPT] was also isolated and its X-ray molecular structure determined.

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hal-00451861 , version 1 (01-02-2010)

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F. Carre, Rjp Corriu, E. Lancelle-Beltran, A. Mehdi, C. Reye, et al.. X-ray crystal structures of copper(II) and cobalt(II) complexes with Schiff base ligands. Reactivity towards dioxygen. Dalton Transactions, 2003, pp.3211-3215. ⟨10.1039/b304032a⟩. ⟨hal-00451861⟩
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