Self-organized heteroditopic macrocyclic superstructures - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Organic Letters Année : 2003

Self-organized heteroditopic macrocyclic superstructures

Mihai Barboiu
G. Vaughan
Arie van Der Lee

Résumé

The synthesis of heteroditopic macrocyclic ureido receptors and of their NaX complexes is described. NMR studies and determination of the crystal structure show the formation of self-organized dimeric or polymeric superstructures by a cooperative macrocyclic cation complexation, anion-hydrogen bonding, and pi-pi stacking interactions. Membrane transport experiments show a direct relation between the synergetic ion-pair recognition and the transport properties of these molecular information transfer devices.
Fichier non déposé

Dates et versions

hal-00451854 , version 1 (01-02-2010)

Identifiants

Citer

Mihai Barboiu, G. Vaughan, Arie van Der Lee. Self-organized heteroditopic macrocyclic superstructures. Organic Letters, 2003, 5, pp.3073-3076. ⟨10.1021/ol035096r⟩. ⟨hal-00451854⟩
20 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More