<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-00447589</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-21T22:27:14+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Synthesis and Modification of Alternating Copolymers Based on Vinyl Ethers, Chlorotrifluoroethylene, and hexafluoropropylene</title>
            <author role="aut">
              <persName>
                <forename type="first">David</forename>
                <surname>Valade</surname>
              </persName>
              <idno type="halauthorid">233597-0</idno>
              <affiliation ref="#struct-24492"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Frédéric</forename>
                <surname>Boschet</surname>
              </persName>
              <email type="md5">6b506ed690eff8828f07c3af0acf3f7b</email>
              <email type="domain">enscm.fr</email>
              <idno type="idhal" notation="numeric">859881</idno>
              <idno type="halauthorid" notation="string">390144-859881</idno>
              <affiliation ref="#struct-24492"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Bruno</forename>
                <surname>Ameduri</surname>
              </persName>
              <email type="md5">fd6d3fad96c8ea31010f5650dd6ace9e</email>
              <email type="domain">enscm.fr</email>
              <idno type="idhal" notation="string">bruno-ameduri</idno>
              <idno type="idhal" notation="numeric">743176</idno>
              <idno type="halauthorid" notation="string">5333-743176</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/P-3667-2017</idno>
              <idno type="IDREF">https://www.idref.fr/033444722</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-4217-6664</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/P-3667-2017</idno>
              <affiliation ref="#struct-24492"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Bruno</forename>
                <surname>Ameduri</surname>
              </persName>
              <email type="md5">fd6d3fad96c8ea31010f5650dd6ace9e</email>
              <email type="domain">enscm.fr</email>
            </editor>
            <funder>projet PACo (Alcapac)</funder>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2010-01-18 16:13:12</date>
              <date type="whenModified">2024-04-11 13:08:13</date>
              <date type="whenReleased">2010-01-18 16:36:48</date>
              <date type="whenProduced">2009</date>
              <date type="whenEndEmbargoed">2010-01-18</date>
              <ref type="file" target="https://hal.science/hal-00447589v1/document">
                <date notBefore="2010-01-18"/>
              </ref>
              <ref type="file" subtype="author" n="1" target="https://hal.science/hal-00447589v1/file/DV_3_Manuscript_v9_Macromol.pdf" id="file-447589-367342">
                <date notBefore="2010-01-18"/>
              </ref>
              <ref type="annex" subtype="other" n="0" target="https://hal.science/hal-00447589v1/file/Figure1.jpg" id="file-447589-367338">
                <date notBefore="2010-01-18"/>
              </ref>
              <ref type="annex" subtype="other" n="0" target="https://hal.science/hal-00447589v1/file/Figure2.jpg" id="file-447589-367337">
                <date notBefore="2010-01-18"/>
              </ref>
              <ref type="annex" subtype="other" n="0" target="https://hal.science/hal-00447589v1/file/Figure3.jpg" id="file-447589-367336">
                <date notBefore="2010-01-18"/>
              </ref>
              <ref type="annex" subtype="other" n="0" target="https://hal.science/hal-00447589v1/file/Figure4.jpg" id="file-447589-367332">
                <date notBefore="2010-01-18"/>
              </ref>
              <ref type="annex" subtype="other" n="0" target="https://hal.science/hal-00447589v1/file/Figure5.jpg" id="file-447589-367340">
                <date notBefore="2010-01-18"/>
              </ref>
              <ref type="annex" subtype="other" n="0" target="https://hal.science/hal-00447589v1/file/Figure6.jpg" id="file-447589-367335">
                <date notBefore="2010-01-18"/>
              </ref>
              <ref type="annex" subtype="other" n="0" target="https://hal.science/hal-00447589v1/file/Figure7.jpg" id="file-447589-367333">
                <date notBefore="2010-01-18"/>
              </ref>
              <ref type="annex" subtype="other" n="0" target="https://hal.science/hal-00447589v1/file/Figure8.jpg" id="file-447589-367339">
                <date notBefore="2010-01-18"/>
              </ref>
              <ref type="externalLink" target="http://hal.archives-ouvertes.fr/docs/00/44/75/89/PDF/DV_3_Manuscript_v9_Macromol.pdf"/>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="121632">
                <persName>
                  <forename>Bruno</forename>
                  <surname>Ameduri</surname>
                </persName>
                <email type="md5">fd6d3fad96c8ea31010f5650dd6ace9e</email>
                <email type="domain">enscm.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-00447589</idno>
            <idno type="halUri">https://hal.science/hal-00447589</idno>
            <idno type="halBibtex">valade:hal-00447589</idno>
            <idno type="halRefHtml">&lt;i&gt;Macromolecules&lt;/i&gt;, 2009, 42, pp.7689-7700. &lt;a target="_blank" href="https://dx.doi.org/10.1021/ma900860u"&gt;&amp;#x27E8;10.1021/ma900860u&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Macromolecules, 2009, 42, pp.7689-7700. &amp;#x27E8;10.1021/ma900860u&amp;#x27E9;</idno>
            <availability status="restricted">
              <licence target="https://about.hal.science/hal-authorisation-v1/">HAL Authorization<ref corresp="#file-447589-367342"/><ref corresp="#file-447589-367338"/><ref corresp="#file-447589-367337"/><ref corresp="#file-447589-367336"/><ref corresp="#file-447589-367332"/><ref corresp="#file-447589-367340"/><ref corresp="#file-447589-367335"/><ref corresp="#file-447589-367333"/><ref corresp="#file-447589-367339"/></licence>
            </availability>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="UNIV-MONTP1">Université Montpellier I</idno>
            <idno type="stamp" n="UNIV-MONTP2">Université Montpellier II - Sciences et Techniques du Languedoc</idno>
            <idno type="stamp" n="ENSC-MONTPELLIER">Ecole Nationale Supérieure de Chimie de Montpellier</idno>
            <idno type="stamp" n="ICG">Institut Charles Gerhardt - Institut de Chimie Moléculaire et des Matériaux de Montpellier</idno>
            <idno type="stamp" n="CHIMIE">Chimie</idno>
            <idno type="stamp" n="UNIV-MONTPELLIER">Université de Montpellier</idno>
            <idno type="stamp" n="UM1-UM2" corresp="UNIV-MONTPELLIER">Université Montpellier 1 - Université Montpellier 2</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Synthesis and Modification of Alternating Copolymers Based on Vinyl Ethers, Chlorotrifluoroethylene, and hexafluoropropylene</title>
                <author role="aut">
                  <persName>
                    <forename type="first">David</forename>
                    <surname>Valade</surname>
                  </persName>
                  <idno type="halauthorid">233597-0</idno>
                  <affiliation ref="#struct-24492"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Frédéric</forename>
                    <surname>Boschet</surname>
                  </persName>
                  <email type="md5">6b506ed690eff8828f07c3af0acf3f7b</email>
                  <email type="domain">enscm.fr</email>
                  <idno type="idhal" notation="numeric">859881</idno>
                  <idno type="halauthorid" notation="string">390144-859881</idno>
                  <affiliation ref="#struct-24492"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Bruno</forename>
                    <surname>Ameduri</surname>
                  </persName>
                  <email type="md5">fd6d3fad96c8ea31010f5650dd6ace9e</email>
                  <email type="domain">enscm.fr</email>
                  <idno type="idhal" notation="string">bruno-ameduri</idno>
                  <idno type="idhal" notation="numeric">743176</idno>
                  <idno type="halauthorid" notation="string">5333-743176</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/P-3667-2017</idno>
                  <idno type="IDREF">https://www.idref.fr/033444722</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-4217-6664</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/P-3667-2017</idno>
                  <affiliation ref="#struct-24492"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">16518</idno>
                <idno type="issn">0024-9297</idno>
                <idno type="eissn">1520-5835</idno>
                <title level="j">Macromolecules</title>
                <imprint>
                  <publisher>American Chemical Society</publisher>
                  <biblScope unit="volume">42</biblScope>
                  <biblScope unit="pp">7689–7700</biblScope>
                  <date type="datePub">2009</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1021/ma900860u</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="it">alkaline fuel cell</term>
                <term xml:lang="it">fluorinated copolymers</term>
                <term xml:lang="it">ammonium groups</term>
                <term xml:lang="it">radical copolymerization</term>
                <term xml:lang="it">fluorinated olefins</term>
                <term xml:lang="it">chlorotrifluoroethylene</term>
                <term xml:lang="it">hexafluoropropylene</term>
              </keywords>
              <classCode scheme="halDomain" n="chim.poly">Chemical Sciences/Polymers</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>Fluorinated copolymers bearing ammonium groups were prepared by radical copolymerization of fluorinated olefins (chlorotrifluoroethylene, hexafluoropropylene) with different vinyl ethers (2-chloroethyl, cyclohexyl, n-butyl, and ethyl vinyl ethers) followed by the cationization of these copolymers with trimethylamine. Copolymers were obtained in high yield (generally &gt;85%), with molecular weights ranging from 8000 to 25 000 g mol-1. From elemental analysis as well as 1H and 19FNMR spectroscopy, the alternating structure of these polymers was confirmed. The chemical modification of these copolymers consisted of a two-step reaction: (i) the replacement of the chlorine atom by an iodine atom followed by (ii) the substitution of the halogen atom by the trimethylamine into a quaternary ammonium. The resulting copolymers were characterized with the usual techniques to assess their compositions and structures. Their thermal analyses, in dynamic mode, under air, showed decomposition temperatures (Td,10%) higher than 200 C. Electrochemical properties of some of these polymers were also studied, showing ionic exchange capacities (IEC) ranging from 0.50 to 0.75 mequiv g-1 (theoretical IEC up to 3.63 mequiv g-1) and water uptake of 13-25%.</p>
            </abstract>
            <particDesc>
              <org type="consortium">projet PACo (Alcapac)</org>
            </particDesc>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-24492" status="OLD">
          <idno type="ISNI">0000000123688723</idno>
          <idno type="RNSR">200711918D</idno>
          <idno type="ROR">https://ror.org/028wq3277</idno>
          <orgName>Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier</orgName>
          <orgName type="acronym">ICGM ICMMM</orgName>
          <date type="start">2006-01-01</date>
          <date type="end">2014-12-31</date>
          <desc>
            <address>
              <addrLine>Place Eugène Bataillon - Bâtiment 17 - CC1700- 34095 Montpellier cedex 5</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.icgm.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-42570" type="direct"/>
            <relation active="#struct-92690" type="direct"/>
            <relation active="#struct-300370" type="direct"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UMR5253" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-42570" status="OLD">
          <orgName>Université Montpellier 1</orgName>
          <orgName type="acronym">UM1</orgName>
          <date type="end">2014-12-31</date>
          <desc>
            <address>
              <addrLine>5, boulevard Henri IV - CS 19044 - 34967 Montpellier cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-montp1.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-92690" status="OLD">
          <orgName>Université Montpellier 2 - Sciences et Techniques</orgName>
          <orgName type="acronym">UM2</orgName>
          <date type="end">2014-12-31</date>
          <desc>
            <address>
              <addrLine>Place Eugène Bataillon - 34095 Montpellier cedex 5</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-montp2.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-300370" status="OLD">
          <idno type="ROR">https://ror.org/03sgyqj04</idno>
          <orgName>Ecole Nationale Supérieure de Chimie de Montpellier</orgName>
          <orgName type="acronym">ENSCM</orgName>
          <date type="end">2021-12-31</date>
          <desc>
            <address>
              <addrLine>8 Rue de l'Ecole Normale 34296 Montpellier Cedex 5</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.enscm.fr</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>