The vibrational levels of methane obtained from analyses of high-resolution spectra - Archive ouverte HAL
Article Dans Une Revue Journal of Quantitative Spectroscopy and Radiative Transfer Année : 2006

The vibrational levels of methane obtained from analyses of high-resolution spectra

Résumé

Methane and its tetrahedral isotopologues are spherical-top molecules whose high-resolution rovibrational spectra can only be analyzed in detail, thanks to sophisticated symmetry-adapted tensorial models. However, the effective Hamiltonian parameters of such models do not give direct access to the positions of the vibrational sublevels. In this paper, we present a calculation of the vibrational level positions for 12CH4, 13CH4, 12CD4 and 13CD4 performed using the effective Hamiltonian parameters obtained through recent analyses. We also include the results of a re-analysis of the octad system of 12CH4 performed with a higher order of the development which slightly improves the previous work on this polyad.

Dates et versions

hal-00437080 , version 1 (29-11-2009)

Identifiants

Citer

Vincent Boudon, Michaël Rey, Michel Loete. The vibrational levels of methane obtained from analyses of high-resolution spectra. Journal of Quantitative Spectroscopy and Radiative Transfer, 2006, 98, pp.394-404. ⟨10.1016/j.jqsrt.2005.06.003⟩. ⟨hal-00437080⟩
56 Consultations
0 Téléchargements

Altmetric

Partager

More