Supramolecular self-organization in constitutional hybrid materials - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue New Journal of Chemistry Année : 2009

Supramolecular self-organization in constitutional hybrid materials

Simona Mihai
  • Fonction : Auteur
  • PersonId : 864840
Adinela Cazacu
  • Fonction : Auteur
  • PersonId : 864089
Gihane Nasr
  • Fonction : Auteur
  • PersonId : 864086
Arie Van-Der-Lee
Mihai Barboiu

Résumé

We present in this paper a new strategy to transcribe the supramolecular dynamic self-organization of the G-quadruplex and ureidocrown ether ion channel-type columnar architectures in constitutional hybrids. In particular, the use of a "dynamic reversible hydrophobic interface'' can render the emerging hybrid mesophases self-adaptive. The reversible hydrophobic interactions allow both supramolecular and inorganic silica components to mutually (synergistically) adapt their spatial constitution during simultaneous (collective) formation of micrometric self-organized hybrid domains. More generally, applying such consideration to materials, leads to the definition of constitutional hybrid materials, in which organic (supramolecular)/inorganic domains are reversibly connected. This might provide new insights into the features that control the design of functional materials.

Dates et versions

hal-00433758 , version 1 (20-11-2009)

Identifiants

Citer

Simona Mihai, Adinela Cazacu, Carole Arnal Herault, Gihane Nasr, Anca Meffre, et al.. Supramolecular self-organization in constitutional hybrid materials. New Journal of Chemistry, 2009, 337 (11), pp.2335 - 2343. ⟨10.1039/b908641m⟩. ⟨hal-00433758⟩
77 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More