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Article Dans Une Revue Oil & Gas Science and Technology - Revue d'IFP Energies nouvelles Année : 2006

Combining Solid State Physics Concepts and X-Ray Absorption Spectroscopy to Understand DeNOx Catalysis

Résumé

Considering the NO adsorption process, starting from theoretical considerations, evaluation of the variation of the properties of metallic clusters versus their size and composition leads to a prediction of the NO adsorption mode on these nanoentities. Then, based on experimental results obtained mostly through X-ray absorption spectroscopy, we have connected the adsorption mode of the molecule to the behaviour of the metallic cluster following the adsorption process. A simple hypothesis leads us to discuss the catalytic activity of nanometer scale metallic clusters following NO adsorption.
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Dates et versions

hal-00431054 , version 1 (04-02-2019)

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Dominique Bazin, John W. Lynch, G. Treglia, Christine Mottet. Combining Solid State Physics Concepts and X-Ray Absorption Spectroscopy to Understand DeNOx Catalysis. Oil & Gas Science and Technology - Revue d'IFP Energies nouvelles, 2006, 61 (5), pp.677-689. ⟨10.2516/ogst:2006006⟩. ⟨hal-00431054⟩
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