REACTION OF H<sub>2</sub> WITH IRHCL<sub>2</sub>P<sub>2</sub> (P = P<sup>I</sup>PR<sub>3</sub> OR P<sup>t</sup>BU<sub>2</sub>PH) - STEREOELECTRONIC CONTROL OF THE STABILITY OF MOLECULAR H<sub>2</sub> TRANSITION-METAL COMPLEXES - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Journal of the American Chemical Society Année : 1993

REACTION OF H2 WITH IRHCL2P2 (P = PIPR3 OR PtBU2PH) - STEREOELECTRONIC CONTROL OF THE STABILITY OF MOLECULAR H2 TRANSITION-METAL COMPLEXES

Alberto Albinati
  • Fonction : Auteur
Vladimir I. Bakhmutov
  • Fonction : Auteur
Kenneth G. Caulton
  • Fonction : Auteur
Eric Clot
Juergen Eckert
  • Fonction : Auteur
Dmitry G. Gusev
  • Fonction : Auteur
Vladimir V. Grushin
  • Fonction : Auteur
Bryan E. Hauger
  • Fonction : Auteur
Wim T. Klooster
  • Fonction : Auteur
Thomas F. Koetzle
  • Fonction : Auteur
Richard K. Mcmullan
  • Fonction : Auteur
Terence J. Loughlin
  • Fonction : Auteur
John S. Ricci
  • Fonction : Auteur
Alexey B. Vymenits
  • Fonction : Auteur

Résumé

IrHCl2P2 (P = PiPr3) reacts rapidly with H-2 at 25-degrees-C to set up an equilibrium where H-2 binds trans to the original hydride ligand (trans-2). A second slower reaction forms IrH(H2)Cl2P2 (cis-2), where the cis disposition of the chlorides, and also H cis to H-2, was established by neutron diffraction. This molecule (unlike trans-2), shows rapid site exchange between coordinated H and H-2. cis-2 can be induced to lose HCl to form Ir(H)2ClP2 (3). The structure of Ir(H)2Cl(PtBu2Ph)2, an analog of 3, was shown by neutron diffraction to have a planar H2IrCl in a Y shape, with Cl at the base of the Y and a H-Ir-H angle of only 73-degrees. ECP ab initio calculations of IrH2Cl(PH3)2 show that the Y shape with a H-Ir-H angle close to the experimental value has the minimum energy. They also show that the trans-2 isomer of IrH(H2)Cl2(PH3)2 is less stable than the cis-2 isomer by 10.3 kcal/mol. The Ir-H-2 interaction is stronger in cis-2. The rotational barrier has been calculated in the two isomers as 2.3 (trans) and 6.5 (cis) kcal/mol. In agreement with the experimental structure, the H-H bond is found to eclipse preferentially the Ir-H bond in cis-2. The calculations also show that the Ir-H-2 bond dissociation energy is greater in cis-2. It thus appears that the binding ability of a metal fragment not only depends on its ligands but is also linked in a subtle way to its stereochemistry. The J(HD) value for coordinated H-2 in cis-2 is 12 +/- 3 Hz. The implication of this small value and of a T1min(200 MHz) of 38 ms is an H/H distance of 1.07-1.35 angstrom, which compares to the neutron diffraction distance of 1.11(3) angstrom. The Ir-H distances of cis-2 are unprecedented in that the hydride-Ir distance (1.584(13) angstrom) is not shorter than the distances to the H-2 hydrogens (1.537(19) and 1.550(17) angstrom). One of the H-2 hydrogens interacts with chloride of an adjacent molecule to give an infinite hydrogen-bonded polymer. An inelastic neutron scattering spectroscopic study on solid IrHCl2(H2)(PiPr3)2 sets a lower limit on the rotational barrier of the Ir(H2) unit of 2.0 kcal/mol. Ab initio calculations on IrHCl2(H2)(PH3)2 yield a H-H distance in these two isomers of 0.81 and 1.4 angstrom, respectively, showing that the moiety IrHCl2(PH3)2 with chlorides mutually cis is a much stronger reducing agent than that with chlorides trans (and thus H trans to H-2). Crystallographic data: For cis-2 (at 15K), a = 13.008(4) angstrom, b = 11.296 (4) angstrom, c = 16.095(4) angstrom in space group Pna2(1) (Z = 4). For Ir(H)2Cl(PtBu2Ph)2 (at 15K), a = 8.236(2) angstrom, b = 17.024(6) angstrom, c = 20.528(10) angstrom, beta = 96.27(4)degrees in space group P2(1)/c (Z = 4).

Dates et versions

hal-00429126 , version 1 (30-10-2009)

Identifiants

Citer

Alberto Albinati, Vladimir I. Bakhmutov, Kenneth G. Caulton, Eric Clot, Juergen Eckert, et al.. REACTION OF H2 WITH IRHCL2P2 (P = PIPR3 OR PtBU2PH) - STEREOELECTRONIC CONTROL OF THE STABILITY OF MOLECULAR H2 TRANSITION-METAL COMPLEXES. Journal of the American Chemical Society, 1993, 115, pp.7300-7312. ⟨10.1021/ja00069a032⟩. ⟨hal-00429126⟩

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