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Article Dans Une Revue Advances in Carbohydrate Chemistry and Biochemistry Année : 2009

Chapter 6 stereocontrolled synthesis of mannans and rhamnans.

Résumé

The total synthesis of the alpha-mannans, alpha-rhamnans, beta-mannans, and beta-rhamnans is presented according to the overall strategy employed. The alpha-mannans and alpha-rhamnans are discussed in terms of the use of use or not of neighboring-group participation to construct the 1,2-trans-axial glycosidic bond, whereas the beta-mannan and beta-rhamnan syntheses are classified as either direct or indirect, with the latter requiring additional steps post-glycosylation to achieve the 1,2-cis-equatorial glycosidic linkage.
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Dates et versions

hal-00396428 , version 1 (18-06-2009)

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Feng Cai, Baolin Wu, David Crich. Chapter 6 stereocontrolled synthesis of mannans and rhamnans.. Advances in Carbohydrate Chemistry and Biochemistry, 2009, 62, pp.251-309. ⟨10.1016/S0065-2318(09)00006-7⟩. ⟨hal-00396428⟩
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