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Article Dans Une Revue Journal of Polymer Science Part A: Polymer Chemistry Année : 2005

Synthesis of telechelic oligomers by atom transfer radical polymerization: A study of acrylate monomers

Résumé

Different acrylate oligomers were synthesized by atom transfer radical polymerization in the presence of a transfer agent and CuBr/1,1,4,7,10,10-hexamethyltriethylenetetramine. The functionality in bromine was determined by 1H NMR. These oligomers were coupled in the presence of Cu(0) and the ligand 2,2-bipyridine. The coupling yield was determined by size exclusion chromatography and NMR analysis and depended on the nature of the monomer and not on the molecular weight. In other words, the preliminary functionalization of the brominated chain end with styrene increased the coupling yield.

Dates et versions

hal-00381585 , version 1 (06-05-2009)

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Citer

Belkacem Otazaghine, Claudine Boyer, Jean Jacques Robin, B. Boutevin. Synthesis of telechelic oligomers by atom transfer radical polymerization: A study of acrylate monomers. Journal of Polymer Science Part A: Polymer Chemistry, 2005, 43 (11), pp.2377. ⟨10.1002/pola.20700⟩. ⟨hal-00381585⟩
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