Preparative scale enzymatic synthesis of D-sedoheptulose-7-phosphate from β-hydroxypyruvate and D-ribose-5-phosphate - Archive ouverte HAL
Article Dans Une Revue Journal of Molecular Catalysis B: Enzymatic Année : 2009

Preparative scale enzymatic synthesis of D-sedoheptulose-7-phosphate from β-hydroxypyruvate and D-ribose-5-phosphate

Résumé

An enzymatic method for ready access to D-sedoheptulose-7-phosphate on a preparative scale was developed, based on the irreversible transketolase-catalyzed reaction: β-hydroxypyruvate + D-ribose-5- phosphate → D-sedoheptulose-7-phosphate. D-Sedoheptulose-7-phosphate disodium salt was obtained in 81% overall yield determined using a standard curve obtained by LC/MS/MS.

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Catalyse
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Dates et versions

hal-00366191 , version 1 (06-03-2009)

Identifiants

  • HAL Id : hal-00366191 , version 1

Citer

Franck Charmantray, Virgil Hélaine, Bertrand Legeret, Laurence Hecquet. Preparative scale enzymatic synthesis of D-sedoheptulose-7-phosphate from β-hydroxypyruvate and D-ribose-5-phosphate. Journal of Molecular Catalysis B: Enzymatic, 2009, 57, pp.6-9. ⟨hal-00366191⟩
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