Selective anodic preparation of 1D or 2D electroactive deposits from 5,15-bis-(9H-fluoren-2-yl)-10,20-diphenyl porphyrins - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Journal of electroanalytical chemistry and interfacial electrochemistry Année : 2007

Selective anodic preparation of 1D or 2D electroactive deposits from 5,15-bis-(9H-fluoren-2-yl)-10,20-diphenyl porphyrins

Résumé

The synthesis and the electrochemical studies of 5,15-bis-(9H-fluoren-2-yl)-10,20-diphenyl porphyrins, H2DFDPP and ZnDFDPP, are presented. Their anodic oxidation at low or high potentials lead selectively to insoluble 1D or 2D electroactive deposits. Electrochemical restructuring of 1D polymeric wires into 2D polymeric films is also demonstrated.

Dates et versions

hal-00355413 , version 1 (22-01-2009)

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Christine Paul-Roth, Joëlle Rault-Berthelot, Gérard Simonneaux, Julien Letessier, Jean-François Bergamini. Selective anodic preparation of 1D or 2D electroactive deposits from 5,15-bis-(9H-fluoren-2-yl)-10,20-diphenyl porphyrins. Journal of electroanalytical chemistry and interfacial electrochemistry, 2007, 606 (2), pp.103-116. ⟨10.1016/j.jelechem.2007.06.003⟩. ⟨hal-00355413⟩
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