Selective anodic preparation of 1D or 2D electroactive deposits from 5,15-bis-(9H-fluoren-2-yl)-10,20-diphenyl porphyrins - Archive ouverte HAL Access content directly
Journal Articles Journal of electroanalytical chemistry and interfacial electrochemistry Year : 2007

Selective anodic preparation of 1D or 2D electroactive deposits from 5,15-bis-(9H-fluoren-2-yl)-10,20-diphenyl porphyrins

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Abstract

The synthesis and the electrochemical studies of 5,15-bis-(9H-fluoren-2-yl)-10,20-diphenyl porphyrins, H2DFDPP and ZnDFDPP, are presented. Their anodic oxidation at low or high potentials lead selectively to insoluble 1D or 2D electroactive deposits. Electrochemical restructuring of 1D polymeric wires into 2D polymeric films is also demonstrated.

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hal-00355413 , version 1 (22-01-2009)

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Christine Paul-Roth, Joëlle Rault-Berthelot, Gérard Simonneaux, Julien Letessier, Jean-François Bergamini. Selective anodic preparation of 1D or 2D electroactive deposits from 5,15-bis-(9H-fluoren-2-yl)-10,20-diphenyl porphyrins. Journal of electroanalytical chemistry and interfacial electrochemistry, 2007, 606 (2), pp.103-116. ⟨10.1016/j.jelechem.2007.06.003⟩. ⟨hal-00355413⟩
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