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Article Dans Une Revue International Journal of Biological Macromolecules Année : 2008

Bicompartmentalized polymer particles by tandem ROMP and ATRP in miniemulsion

Résumé

This Study describes an original approach to prepare biphasic particles by simultaneous ring-opening metathesis polymerization (ROMP) of norbornene and atom-transfer radical polymerization (ATRP) of methyl methacrylate under miniemulsion conditions. A single water-soluble ruthenium macrocatalyst was used to initiate ROMP and mediate ATRP. All situations led to high conversions, and well-distributed particles containing two incompatible homopolymers grown under controlled conditions could indeed be prepared.
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Dates et versions

hal-00340556 , version 1 (21-11-2008)

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Cédric Airaud, Valérie Héroguez, Yves Gnanou. Bicompartmentalized polymer particles by tandem ROMP and ATRP in miniemulsion. International Journal of Biological Macromolecules, 2008, 41 (9), pp.3015-3022. ⟨10.1021/ma702682s⟩. ⟨hal-00340556⟩
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