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Article Dans Une Revue Chemical Communications Année : 2008

Methylidynearsine (HC≡As): Synthesis and direct characterization by UV-photoelectron spectroscopy and mass spectrometry

Résumé

he dehydrohalogenation of gaseous dichloromethylarsine on solid base led to chloromethylidenearsine and, at higher temperature of the base, to methylidynearsine, the third unsubstituted heteroalkyne unambiguously synthesized up to now. Graphical abstract image for this article (ID: b806771f)

Dates et versions

hal-00340029 , version 1 (19-11-2008)

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Jean-Claude Guillemin, Anna Chrostowska, Alain Dargelos, T.X.M. Tquyen, Alain Graciaa, et al.. Methylidynearsine (HC≡As): Synthesis and direct characterization by UV-photoelectron spectroscopy and mass spectrometry. Chemical Communications, 2008, 35, pp.4204-4206. ⟨10.1039/b806771f⟩. ⟨hal-00340029⟩
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