Water-Soluble Triphenylphosphane-3,3',3''-tricarboxylate (m-TPPTC) Ligand and Methylated Cyclodextrins: A New Combination for Biphasic Rhodium-Catalyzed Hydroformylation of Higher Olefins - Archive ouverte HAL Accéder directement au contenu
N°Spécial De Revue/Special Issue Advanced Synthesis and Catalysis Année : 2006

Water-Soluble Triphenylphosphane-3,3',3''-tricarboxylate (m-TPPTC) Ligand and Methylated Cyclodextrins: A New Combination for Biphasic Rhodium-Catalyzed Hydroformylation of Higher Olefins

S. Tilloy
F. Hapiot
J.P. Genêt
  • Fonction : Auteur
V. Michelet
  • Fonction : Auteur
E. Monflier

Résumé

The methylated cyclodextrins/m-TPPTC [tris(m-carboxyphenyl)phosphane trilithium salt] couples proved to be more efficient than the well-known methylated cyclodextrins/TPPTS [tris(m-sulfonatophenyl)phosphane trisodium salt] systems in terms of activities and selectivities to perform the Rh-catalyzed hydroformylation of higher olefins in an aqueous-organic system. The interactions cyclodextrins/m-TPPTC have been fully studied by NMR spectroscopy.

Domaines

Chimie
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Dates et versions

hal-00322863 , version 1 (18-09-2008)

Identifiants

  • HAL Id : hal-00322863 , version 1

Citer

S. Tilloy, E. Genin, F. Hapiot, David Landy, Sophie Fourmentin, et al.. Water-Soluble Triphenylphosphane-3,3',3''-tricarboxylate (m-TPPTC) Ligand and Methylated Cyclodextrins: A New Combination for Biphasic Rhodium-Catalyzed Hydroformylation of Higher Olefins. Advanced Synthesis and Catalysis, 348 (12-13), pp.1547-1552, 2006, Special Issue:Multiphase Catalysis, Green Solvents and Immobilization. ⟨hal-00322863⟩
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