Role of ceria-supported metal catalysts (Ru, Pd, Pt) in wet air oxidation of nitrogen and oxygen containing compounds [invited paper] - Archive ouverte HAL
Article Dans Une Revue Topics in Catalysis Année : 2005

Role of ceria-supported metal catalysts (Ru, Pd, Pt) in wet air oxidation of nitrogen and oxygen containing compounds [invited paper]

Résumé

Catalytic Wet Air Oxidation (CWAO) of aniline, phenol, carboxylic acids and ammonia was carried out in a batch reactor over noble metals (Ru, Pd, Pt) supported on ceria. Ruthenium is very active for the conversion of a wide range of organic compounds and selective into carbon dioxide. The ability of ceria to transfer oxygen is essential for good performances in CWAO. However, Ru/CeO2 is not selective for ammonia oxidation into N2 . Addition of small amount of Pd enhances both activity and selectivity of Ru in this reaction. Finally, oxidation of nitrogenous organic compounds requires moderate temperature and oxygen pressure and needs to adjust the oxidizing capacity of the catalyst.

Dates et versions

hal-00288588 , version 1 (17-06-2008)

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Citer

Jacques Barbier, Laetitia Oliviero, B. Renard, Daniel Duprez. Role of ceria-supported metal catalysts (Ru, Pd, Pt) in wet air oxidation of nitrogen and oxygen containing compounds [invited paper]. Topics in Catalysis, 2005, 33 (1-4), pp.77-86. ⟨10.1007/s11244-005-2509-1⟩. ⟨hal-00288588⟩

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