Raman bands of double-wall carbon nanotubes : comparison with single- and triple-wall carbon nanotubes, and influence of annealing and electron irradiation - Archive ouverte HAL
Article Dans Une Revue Journal of Raman Spectroscopy Année : 2007

Raman bands of double-wall carbon nanotubes : comparison with single- and triple-wall carbon nanotubes, and influence of annealing and electron irradiation

Pascal Puech
E. Flahaut
A. Bassil
  • Fonction : Auteur
T. Juffmann
  • Fonction : Auteur
Wolfgang Bacsa

Résumé

We compare the G and G'2D bands of single-, double- and triple-wall carbon nanotubes (CNTs). We observe that the band shape is sensitive to the number of walls of the CNTs. For single-wall carbon nanotubes (SWCNTs), the G band is composed of two distinct contributions G+ and G−, while the G band for double-wall nanotubes is composed of one band with twomain contributions from the inner and the outer tube. The G'2D band can be fitted with one Lorentzian for single-wall tubes, while two distinct contributions are observed for double-wall carbon nanotubes (DWCNTs). Considerable variations of the G'2D band are found with similar first order Raman spectra. Annealing influences the D- and RBM-band intensities. Electron irradiation has the effect of decreasing the G- and D-band wavenumbers but does not enhance the D-band intensity considerably. The down-shifts of the G- and D-band wavenumbers are correlated and are the same for two excitation wavelengths. This is consistent with the scattering of phonons around the K-point.
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Dates et versions

hal-00287924 , version 1 (13-06-2008)

Identifiants

  • HAL Id : hal-00287924 , version 1

Citer

Pascal Puech, E. Flahaut, A. Bassil, T. Juffmann, Francois Beuneu, et al.. Raman bands of double-wall carbon nanotubes : comparison with single- and triple-wall carbon nanotubes, and influence of annealing and electron irradiation. Journal of Raman Spectroscopy, 2007, 38, pp.714. ⟨hal-00287924⟩
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