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Article Dans Une Revue Macromolecular Rapid Communications Année : 2008

Red Ionic Water-Soluble Imidazolium-Containing Polydiacetylene

Résumé

Synthesis of a water-soluble polydiacetylene has been achieved by topochemical polymerization in the solid state of the bis(N-methylimidazolium)diacetylene monomer. Structural characterization for the monomer by X-ray diffraction and NMR spectroscopy supports a photopolymerization initiated at the surface. Characterization of the polymer (NMR, UV and Raman spectroscopy, and dynamic light scattering) is given along with a molecular modelling interpretation of the polymerization in the solid state.

Dates et versions

hal-00273356 , version 1 (15-04-2008)

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Citer

Kamel Chougrani, Jérôme Deschamps, Sylvain Dutremez, Arie van Der Lee, Thierry Barisien, et al.. Red Ionic Water-Soluble Imidazolium-Containing Polydiacetylene. Macromolecular Rapid Communications, 2008, 29, pp.580-586. ⟨10.1002/marc.200700704⟩. ⟨hal-00273356⟩
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