Structural Rearrangements Induced by Photoexcitation in a RbCoFe Prussian Blue Derivative
Résumé
Systems that undergo a reversible and controlled change of their physical properties offer appealing perspectives for the elaboration of electronic devices. Evidence of a photomag- netic effect in a CoFe Prussian blue analogue was a milestone in this research area and showed that molecular excitation can induce long-range magnetic order.[1] In the face-centered cubic structure of the CoFe Prussian blue analogues of chemical formula MxCo4[Fe(CN)6](8+x)/3&(4