Quantitative IR characterization of the acidity of various oxide catalysts - Archive ouverte HAL
Article Dans Une Revue Microporous and Mesoporous Materials Année : 2005

Quantitative IR characterization of the acidity of various oxide catalysts

Résumé

The integrated molar absorption coefficients of the infrared bands characteristic of adsorbed lutidine (2,6-dimethylpyridine) were determined for the purpose of quantifying the acid sites of solid catalysts. The integrated molar absorption coefficients were measured for lutidine adsorbed through H-bonding, coordination to Lewis sites and protonation on Brønsted acid sites. The solids were chosen to present all possible bondings with lutidine and to cover a wide range of common types of catalysts or supports: silica, phosphated silica, HY zeolite, alumina, zirconia, WOx supported on zirconia and NbOx supported on zirconia.
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Dates et versions

hal-00162515 , version 1 (13-07-2007)

Identifiants

  • HAL Id : hal-00162515 , version 1

Citer

T. Onfroy, G. Clet, M. Houalla. Quantitative IR characterization of the acidity of various oxide catalysts. Microporous and Mesoporous Materials, 2005, 82, pp.99-104. ⟨hal-00162515⟩
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