Induced decomposition of acetylenic peroxides - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Bulletin Des Sociétés Chimiques Belges Année : 1996

Induced decomposition of acetylenic peroxides

Laurent Lemée

Résumé

Acetylenic peroxides react as radicals in good hydrogen-donor solvents. Addition to the triple bond leads to monoadducts and attack on the O-O bond gives unsaturated acetals. The intermediate vinyl radical obtained in the first case does not seem to lead to homolytic intramolecular substitution. Unlike their ethylenic homologous these compounds are not unsaturated heterocycle precursors.

Domaines

Chimie organique
Fichier non déposé

Dates et versions

hal-00160759 , version 1 (07-07-2007)

Identifiants

  • HAL Id : hal-00160759 , version 1

Citer

Laurent Lemée, Evelyne Montaudon, Marie-Joseph Bourgeois. Induced decomposition of acetylenic peroxides. Bulletin Des Sociétés Chimiques Belges, 1996, 105 (8), pp.467-472. ⟨hal-00160759⟩
12 Consultations
0 Téléchargements

Partager

Gmail Facebook X LinkedIn More