Equilibrium and electrokinetic phenomena in charged porous media from microscopic and mesoscopic models: electro-osmosis in montmorillonite - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Molecular Physics Année : 2003

Equilibrium and electrokinetic phenomena in charged porous media from microscopic and mesoscopic models: electro-osmosis in montmorillonite

Résumé

Ion concentration profiles and electro-osmosis have been theoretically investigated by complementary methods. The counterion profiles of these charged porous media are obtained from microscopic (molecular dynamics) and mesoscopic (Brownian dynamics and Poisson-Boltzmann equation) models. Thus, the limit of validity of the more macroscopic approaches has been quantified. The electro-osmotic flow is evaluated from a similar multi-scale description. A proper evaluation of the Kubo relations adapted to this dynamical process allowed the value of this transport quantity to be obtained from the microscopic model. The comparison with the classical Smoluchowski theory of this electrokinetic phenomenon shows that the latter cannot be applied unless slip hydrodynamic boundary conditions are taken into account. The corresponding slipping length is roughly equal to 6 Å.
Fichier non déposé

Dates et versions

hal-00143676 , version 1 (26-04-2007)

Identifiants

Citer

V. Marry, Jean-François Dufrêche, Marie Jardat, P. Turq. Equilibrium and electrokinetic phenomena in charged porous media from microscopic and mesoscopic models: electro-osmosis in montmorillonite. Molecular Physics, 2003, 101, pp.3111. ⟨10.1080/00268970310001626432⟩. ⟨hal-00143676⟩
81 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More