<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-00104262</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-19T02:45:32+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Catalytic dense membranes of doped Bi4V2O11 (BIMEVOX) for selective partial oxidation: chemistry of defects versus catalysis</title>
            <author role="aut">
              <persName>
                <forename type="first">Axel</forename>
                <surname>Löfberg</surname>
              </persName>
              <email type="md5">0cf4e136e06c217501af03b93d3505b5</email>
              <email type="domain">univ-lille.fr</email>
              <idno type="idhal" notation="string">axel-lofberg</idno>
              <idno type="idhal" notation="numeric">5890</idno>
              <idno type="halauthorid" notation="string">1682-5890</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/B-5552-2012</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-8537-3011</idno>
              <idno type="IDREF">https://www.idref.fr/149911025</idno>
              <affiliation ref="#struct-3209"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Hervé</forename>
                <surname>Bodet</surname>
              </persName>
              <idno type="halauthorid">131570-0</idno>
              <affiliation ref="#struct-3209"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Caroline</forename>
                <surname>Pirovano</surname>
              </persName>
              <email type="md5">d6ddd77c8b469f3993873ab164250376</email>
              <email type="domain">ensc-lille.fr</email>
              <idno type="idhal" notation="string">caroline-pirovano</idno>
              <idno type="idhal" notation="numeric">1334515</idno>
              <idno type="halauthorid" notation="string">131461-1334515</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-8028-2030</idno>
              <affiliation ref="#struct-3209"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Marlu César</forename>
                <surname>Steil</surname>
              </persName>
              <idno type="halauthorid">171306-0</idno>
              <affiliation ref="#struct-3209"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Rose-Noëlle</forename>
                <surname>Vannier</surname>
              </persName>
              <email type="md5">f8cfa56da961f071a82d2c785d6e780b</email>
              <email type="domain">ensc-lille.fr</email>
              <idno type="idhal" notation="string">rose-noelle-vannier</idno>
              <idno type="idhal" notation="numeric">19387</idno>
              <idno type="halauthorid" notation="string">1683-19387</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-7494-9230</idno>
              <idno type="IDREF">https://www.idref.fr/12276658X</idno>
              <affiliation ref="#struct-3209"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Elisabeth</forename>
                <surname>Bordes-Richard</surname>
              </persName>
              <idno type="halauthorid">131462-0</idno>
              <affiliation ref="#struct-3209"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Axel</forename>
                <surname>Löfberg</surname>
              </persName>
              <email type="md5">0cf4e136e06c217501af03b93d3505b5</email>
              <email type="domain">univ-lille.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2006-10-06 10:58:53</date>
              <date type="whenModified">2026-02-07 05:07:29</date>
              <date type="whenReleased">2006-10-06 11:01:09</date>
              <date type="whenProduced">2006</date>
              <date type="whenEndEmbargoed">2006-10-06</date>
              <ref type="file" target="https://hal.science/hal-00104262v1/document">
                <date notBefore="2006-10-06"/>
              </ref>
              <ref type="file" n="1" target="https://hal.science/hal-00104262v1/file/TopCat38-169.pdf" id="file-104262-26039">
                <date notBefore="2006-10-06"/>
              </ref>
              <ref type="externalLink" target="https://hal.archives-ouvertes.fr/hal-00104262/file/TopCat38-169.pdf"/>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="103745">
                <persName>
                  <forename>Axel</forename>
                  <surname>Löfberg</surname>
                </persName>
                <email type="md5">0cf4e136e06c217501af03b93d3505b5</email>
                <email type="domain">univ-lille.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-00104262</idno>
            <idno type="halUri">https://hal.science/hal-00104262</idno>
            <idno type="halBibtex">lofberg:hal-00104262</idno>
            <idno type="halRefHtml">&lt;i&gt;Topics in Catalysis&lt;/i&gt;, 2006, 38, pp.169-179. &lt;a target="_blank" href="https://dx.doi.org/10.1007/s11244-006-0082-x"&gt;&amp;#x27E8;10.1007/s11244-006-0082-x&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Topics in Catalysis, 2006, 38, pp.169-179. &amp;#x27E8;10.1007/s11244-006-0082-x&amp;#x27E9;</idno>
            <availability status="restricted">
              <licence target="https://about.hal.science/hal-authorisation-v1/">HAL Authorization<ref corresp="#file-104262-26039"/></licence>
            </availability>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="UNIV-ARTOIS">Université d'Artois</idno>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="UCCS">Unité de Catalyse et de Chimie du Solide</idno>
            <idno type="stamp" n="UNIV-LILLE">Université de Lille</idno>
            <idno type="stamp" n="TEST2-HALCNRS">TEST2-HALCNRS</idno>
            <idno type="stamp" n="UCCS-CASETE">UCCS-CASETE</idno>
            <idno type="stamp" n="UCCS-MISSP">UCCS-MISSP</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="1">Not set</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Catalytic dense membranes of doped Bi4V2O11 (BIMEVOX) for selective partial oxidation: chemistry of defects versus catalysis</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Axel</forename>
                    <surname>Löfberg</surname>
                  </persName>
                  <email type="md5">0cf4e136e06c217501af03b93d3505b5</email>
                  <email type="domain">univ-lille.fr</email>
                  <idno type="idhal" notation="string">axel-lofberg</idno>
                  <idno type="idhal" notation="numeric">5890</idno>
                  <idno type="halauthorid" notation="string">1682-5890</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/B-5552-2012</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-8537-3011</idno>
                  <idno type="IDREF">https://www.idref.fr/149911025</idno>
                  <affiliation ref="#struct-3209"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Hervé</forename>
                    <surname>Bodet</surname>
                  </persName>
                  <idno type="halauthorid">131570-0</idno>
                  <affiliation ref="#struct-3209"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Caroline</forename>
                    <surname>Pirovano</surname>
                  </persName>
                  <email type="md5">d6ddd77c8b469f3993873ab164250376</email>
                  <email type="domain">ensc-lille.fr</email>
                  <idno type="idhal" notation="string">caroline-pirovano</idno>
                  <idno type="idhal" notation="numeric">1334515</idno>
                  <idno type="halauthorid" notation="string">131461-1334515</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-8028-2030</idno>
                  <affiliation ref="#struct-3209"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Marlu César</forename>
                    <surname>Steil</surname>
                  </persName>
                  <idno type="halauthorid">171306-0</idno>
                  <affiliation ref="#struct-3209"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Rose-Noëlle</forename>
                    <surname>Vannier</surname>
                  </persName>
                  <email type="md5">f8cfa56da961f071a82d2c785d6e780b</email>
                  <email type="domain">ensc-lille.fr</email>
                  <idno type="idhal" notation="string">rose-noelle-vannier</idno>
                  <idno type="idhal" notation="numeric">19387</idno>
                  <idno type="halauthorid" notation="string">1683-19387</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-7494-9230</idno>
                  <idno type="IDREF">https://www.idref.fr/12276658X</idno>
                  <affiliation ref="#struct-3209"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Elisabeth</forename>
                    <surname>Bordes-Richard</surname>
                  </persName>
                  <idno type="halauthorid">131462-0</idno>
                  <affiliation ref="#struct-3209"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">19644</idno>
                <idno type="issn">1022-5528</idno>
                <idno type="eissn">1572-9028</idno>
                <title level="j">Topics in Catalysis</title>
                <imprint>
                  <publisher>Springer Verlag [1994-....]</publisher>
                  <biblScope unit="volume">38</biblScope>
                  <biblScope unit="pp">169-179</biblScope>
                  <date type="datePub">2006</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1007/s11244-006-0082-x</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">catalytic dense membrane reactor</term>
                <term xml:lang="en">syngas</term>
                <term xml:lang="en">mild oxidation of propene</term>
                <term xml:lang="en">partial oxidation of propane</term>
                <term xml:lang="en">oxide ion conductivity</term>
                <term xml:lang="en">electronic conductivity</term>
              </keywords>
              <classCode scheme="halDomain" n="chim.cata">Chemical Sciences/Catalysis</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>A catalytic dense membrane reactor (CDMR) is used to physically separate the reaction step from the reoxidation of the catalyst. By decoupling the redox mechanism prevailing in mild oxidation of hydrocarbons, the operating conditions may be optimized resulting in an increase of selectivity. The membranes are made up of BIMEVOX oxides, obtained by partial substitution of V in Γ-Bi4V2O11 by ME (Co, Cu, Ta). Experiments performed on BIMEVOX dense membranes using propene and propane are described in terms of, (i) active sites on polished or unpolished surfaces, (ii) operating conditions (T, pO2 in the high oxygen partial pressure compartment), which determine the selectivity, either to mild oxidation products (acrolein, hexadiene, CO), or to partial oxidation products (CO, H2), and, (iii) nature of ME cations and relative properties. The discussion deals with the respective role of electronic vs. oxide ion conductivities which depend on defects in the structure as well as on the redox properties of cations.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-3209" status="VALID">
          <idno type="IdRef">161608809</idno>
          <idno type="ISNI">0000 0004 0368 3038</idno>
          <idno type="RNSR">200612828X</idno>
          <idno type="ROR">https://ror.org/04vrqzz54</idno>
          <idno type="Wikidata">Q3214445</idno>
          <orgName>Unité de Catalyse et Chimie du Solide - UMR 8181</orgName>
          <orgName type="acronym">UCCS</orgName>
          <date type="start">2006-01-01</date>
          <desc>
            <address>
              <addrLine>Cité Scientifique - Bâtiment C3 - 59655 Villeneuve d'Ascq Cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://uccs.univ-lille.fr/</ref>
          </desc>
          <listRelation>
            <relation name="UMR8181" active="#struct-56711" type="direct"/>
            <relation name="UMR8181" active="#struct-120930" type="direct"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UMR8181" active="#struct-374570" type="direct"/>
            <relation name="UMR8181" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-56711" status="VALID">
          <idno type="IdRef">034634894</idno>
          <idno type="ISNI">000000012364777X</idno>
          <idno type="ROR">https://ror.org/053x9s498</idno>
          <orgName>Université d'Artois</orgName>
          <orgName type="acronym">UA</orgName>
          <date type="start">1992-09-01</date>
          <desc>
            <address>
              <addrLine>9 rue du Temple - BP 10665 - 62030 Arras cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-artois.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-120930" status="VALID">
          <idno type="IdRef">256304629</idno>
          <idno type="ISNI">0000000122034461</idno>
          <idno type="ROR">https://ror.org/01x441g73</idno>
          <orgName>Centrale Lille</orgName>
          <desc>
            <address>
              <addrLine>École Centrale de Lille - Cité Scientifique - CS 20048 59651 Villeneuve d'Ascq Cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://centralelille.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-374570" status="VALID">
          <idno type="IdRef">223446556</idno>
          <idno type="ISNI">0000 0001 2242 6780</idno>
          <idno type="ROR">https://ror.org/02kzqn938</idno>
          <idno type="Wikidata">Q3551621</idno>
          <orgName>Université de Lille</orgName>
          <desc>
            <address>
              <addrLine>EPE Université de Lille. -- 42 rue Paul Duez, 59000 Lille</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.univ-lille.fr/</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>