A new isoreticular class of metal-organic-frameworks with the MIL-88 topology
Résumé
The authors report here a new family of isoreticular MOFs, comprising three larger analogs of the nanoporous metallocarboxylate MIL-88, namely Cr3OXL3.8H2O.py (H2L = terephthalic acid; X = OH, F), Fe3OL13(OAc).H2O.6.6MeOH (H2L1 = 2,6-naphthalenedicarboxylic acid) and Cr3OXL23.23.75H2O.2.46py (H2L2 = 4,4'-biphenyldicarboxylic acid). These solids were synthesized using a controlled SBU approach and the three crystal structures were solved using an original simulation-assisted structure detn. method in direct space.