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Article Dans Une Revue Chemical Physics Letters Année : 2022

Ozone-assisted oxidation of ethylene in a jet-stirred reactor: An experimental and modeling study

Caroline Smith Lewin
  • Fonction : Auteur
Olivier Herbinet
Frédérique Battin-Leclerc

Résumé

Ozone addition is a promising method to achieve improvement and control of combustion/ignition processes due to ozone-derived chemistry. However, the complexity induced by ozonolysis reactions make investigations on O3-assisted oxidation with alkenes still scarce. In this work, the ozone-assisted oxidation of ethylene was studied in a jet-stirred reactor from 300 to 1000 K. The main products were identified and quantified by mass spectrometry/gas chromatography analysis. The mole fractions were then compared to those computed with a kinetic model from the literature. This work provides data for the development of detailed chemical kinetic models relevant to atmospheric and combustion chemistry studies.

Domaines

Chimie
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Dates et versions

hal-03847088 , version 1 (10-11-2022)

Licence

Paternité - Pas d'utilisation commerciale - Pas de modification

Identifiants

Citer

Caroline Smith Lewin, Olivier Herbinet, Frédérique Battin-Leclerc, Jérémy Bourgalais. Ozone-assisted oxidation of ethylene in a jet-stirred reactor: An experimental and modeling study. Chemical Physics Letters, 2022, 806 (18), pp.139986. ⟨10.1016/j.cplett.2022.139986⟩. ⟨hal-03847088⟩
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