Phase transitions in polymorphic materials probed using space-resolved diffusing wave spectroscopy - Laboratoire Charles Coulomb (L2C)
Journal Articles Soft Matter Year : 2018

Phase transitions in polymorphic materials probed using space-resolved diffusing wave spectroscopy

Abstract

We use space-resolved dynamic light scattering in the highly multiple scattering regime (Photon Correlation Imaging Diffusing Wave Spectroscopy, PCI-DWS) to investigate temperature-induced phase transitions in polymorphic materials. We study paraffin wax as a simple model system and chocolate, a prototypical example of fat-based products exhibiting complex, history-dependent phase transitions. We find that microscopic dynamics measured using PCI-DWS show remarkable, non-monotonic behavior upon heating: they transiently accelerate when crossing phase transition and slow down above the transition temperature. Sub-micron resolution measurements of the local drift of the sample surface reveal that the speed-up of the dynamics is due to the strain field induced by the change in density at transition temperature. The transition temperatures obtained from PCI-DWS are found to be in excellent agreement with those inferred from complementary differential scanning calorimetry and X-ray scattering experiments, thereby validating PCI-DWS as a new, powerful tool for the characterization of phase transitions in complex soft matter. Finally, we demonstrate the unique possibilities afforded by space-resolved DWS by investigating the spatially heterogeneous response of poorly manufactured or composite chocolate samples.
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Dates and versions

hal-01896690 , version 1 (16-10-2018)

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Med Yassine Nagazi, Philippe Dieudonne-George, Giovanni Brambilla, Gerard Meunier, Luca Cipelletti. Phase transitions in polymorphic materials probed using space-resolved diffusing wave spectroscopy. Soft Matter, 2018, 14 (31), pp.6439-6448. ⟨10.1039/c8sm00911b⟩. ⟨hal-01896690⟩
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