Spontaneous Emulsification of Organometallic Complexes Applied to the Synthesis of Nanocapsules Active for H<sub>2</sub> Release from Ammonia-Borane - Institut de Chimie Moléculaire de l'Université de Bourgogne
Article Dans Une Revue Langmuir Année : 2024

Spontaneous Emulsification of Organometallic Complexes Applied to the Synthesis of Nanocapsules Active for H2 Release from Ammonia-Borane

Résumé

Herein, we achieved spontaneous emulsification of organometallic precursors to elaborate subμm metal nanocapsules after interfacial reduction. Depending on the proportion of the three components, water, solvent, and the metal precursor, either thermodynamically stable "surfactantfree microemulsions" (SFME) or metastable Ouzo emulsions are formed. We investigated the catalytic transition metals Au, Pd, and Pt, individually or combined, and stabilized by various ligands. Upon reduction of the precursors, either shells of discrete nanoparticles (NPs) or continuous shells were obtained, for the SFME and Ouzo emulsions, respectively. The Au/Pd mixed emulsions lead to a unique structural morphology, in which the Au-Pd nanoparticles are embedded in a continuous submicronic metal shell. The AuNPs are available to grow larger particles within the NP shell using a seeded growth approach. The water-stable and surfactantfree nanocapsules are appealing as catalysts, and, as such, were evaluated for the hydrolysis of ammonia-borane as a promising catalytic strategy for H 2 release from an H-high-content storage material. This work establishes for the first time a genuine activity of water-compatible gold colloids for this reaction.

Domaines

Chimie
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vendredi 28 février 2025
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Dates et versions

hal-04762632 , version 1 (09-09-2024)
hal-04762632 , version 2 (31-10-2024)

Identifiants

Citer

Olivier Gazil, Ludivine Rault, Déborah Iglicki, V. Collière, Gizem Karacaoglan, et al.. Spontaneous Emulsification of Organometallic Complexes Applied to the Synthesis of Nanocapsules Active for H2 Release from Ammonia-Borane. Langmuir, 2024, 40 (32), pp.16824 - 16832. ⟨10.1021/acs.langmuir.4c01307⟩. ⟨hal-04762632v2⟩
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