Through-bond homonuclear correlation experiments in Solid-state NMR applied to quadrupolar nuclei in Al-O-P-O-Al chains. - Conditions Extrêmes et Matériaux : Haute Température et Irradiation Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2006

Through-bond homonuclear correlation experiments in Solid-state NMR applied to quadrupolar nuclei in Al-O-P-O-Al chains.

Résumé

Through-bond homonuclear correlation experiments can be realised in solids between spins of type X, separated by four chemical bonds, in X-O-Y-O-X motives, provided a J coupling 10 between X and Y exists: central transitions of quadrupolar 27Al spins can be correlated via the J2 scalar coupling between 27Al (X) and 31P (Y) in materials featuring Al-O-P-O-Al motives.

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Matériaux
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Dates et versions

hal-00021321 , version 1 (21-03-2006)

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Michaël Deschamps, Franck Fayon, Valérie Montouillout, Dominique Massiot. Through-bond homonuclear correlation experiments in Solid-state NMR applied to quadrupolar nuclei in Al-O-P-O-Al chains.. Chemical Communications, 2006, N/A, pp.1924-1925. ⟨10.1039/b600514d⟩. ⟨hal-00021321⟩

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